IMO, 5 on nitrates is the least of your worries..concentrate on getting back to basics..keep it simple...personally, I would do water changes every two weeks instead of one massive change at a time and stop dosing all products except calcium and Mg until the water chemistry is more stable...if the collection cup on your skimmer is NOT being emptied at least once a week, then you need to adjust..this could be part of the issue..i would increase the flow on the tank to ensure the skimmer is being utilized fully..if you think test kits are bad, then take a water sample to a LFS for them to check, while u are there I would have them check the TDS of your DI water just to make sure it reads 0..there is one level that was not mentioned..PO4, what is the level?
if you dont have a TDS meter or a PO4 kit, I have both and dont mind testing for you..


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I used to have similar problems, but frequent water changes make everything in my tank happy. Replenishes the tank and gets out the junk. Also, how old are your bulbs? I hadn't changed my bulbs in 2 years (time goes by so fast) and we just updated all of them last week... HUGE difference. Everything is brightening up and growing like crazy. Look into BRS Two-Part Dosing. Good luck!